Chapter 1: Chemical Reactions and Equations
Chemical reactions - where substances lose their original identity and change into new substances! Let's explore chemical equations, balancing techniques, types of reactions, and redox processes in action. 🧪 Chemical reactions (chemical reactionएँ) - जहाँ substance अपनी मूल पहचान खोकर नए substanceों में बदलते हैं! चलो, chemical equations, balancing techniques, types of reactions, और redox processes को detail में समझते हैं। 🧪
- A physical change only changes the physical state or appearance of a substance (e.g., melting ice) without forming new substances. एक physical change (physical change) केवल किसी substance की physical state या appearance को बदलता है (जैसे melting ice), इसमें कोई नया substance नहीं बनता।
- A chemical change alters the chemical composition of a substance, breaking and making bonds to create new products with entirely different chemical identities (e.g., rusting iron). एक chemical change (chemical change) किसी substance की chemical composition को बदल देता है, जहाँ bonds टूटने और बनने से बिल्कुल नई chemical identity वाले products बनते हैं (जैसे rusting iron)।
- The Law of Conservation of Mass states that mass can neither be created nor destroyed in a chemical reaction. Law of Conservation of Mass (mass conservation का नियम) कहता है कि किसी भी chemical reaction में mass को न तो create (बनाया) किया जा सकता है और न ही destroy (नष्ट) किया जा सकता है।
1. Chemical Changes रासायनिक परिवर्तन
In our daily life, we witness chemical changes constantly: when milk is left at room temperature during summers and turns sour, when an iron pan or nail is left exposed to a humid atmosphere and rusts, when grapes get fermented, when food is cooked, when food gets digested in our body, and when we respire [NCERT p.1]. In all these situations, the nature and identity of the initial substance have changed. We say a chemical reaction has taken place [NCERT p.1]. रोजमर्रा की जिंदगी में हम लगातार chemical changes (chemical change) देखते हैं: जैसे गर्मी में दूध को कमरे के temperature पर रखने पर वह खट्टा हो जाता है, जब लोहे के तवे या कील को नम हवा (moisture) में छोड़ दिया जाता है और उसमें जंग लग जाता है, जब organूरों का fermentation (किण्वन) होता है, जब खाना पकाया जाता है, जब हमारे शरीर में खाना digest होता है, और जब हम respire (साँस लेते हैं) [NCERT p.1]। इन सभी स्थितियों में, शुरुआती substance का स्वभाव और पहचान बदल जाती है। हम कहते हैं कि यहाँ एक chemical reaction हुई है [NCERT p.1]।
To determine experimentally whether a chemical reaction has occurred, scientists perform specific activities in the laboratory: प्रयोग के जरिए यह पता लगाने के लिए कि क्या कोई chemical reaction हुई है, scientists laboratory में कुछ activities करते हैं:
- Activity 1.1 (Burning of Magnesium): Rub a magnesium ribbon with sandpaper to clean it, hold it with tongs, and burn it using a spirit lamp [NCERT p.1]. The magnesium ribbon burns with a dazzling white flame and changes into a white powder [NCERT p.2]. This white powder is magnesium oxide, formed by the reaction between magnesium and oxygen present in the air [NCERT p.2]. Activity 1.1 (Burning of Magnesium): एक magnesium ribbon को sandpaper से रगड़कर साफ करें, उसे चिमटे (tongs) से पकड़ें, और spirit lamp से जलाएं [NCERT p.1]। Magnesium ribbon एक चमकदार सफेद लौ (dazzling white flame) के साथ जलती है और सफेद पाउडर में बदल जाती है [NCERT p.2]। यह सफेद पाउडर magnesium oxide (मैग्नीशियम ऑक्साइड) है, जो magnesium और हवा में मौजूद oxygen के बीच reaction होने से बनता है [NCERT p.2]।
- Activity 1.2 (Precipitation Reaction): Add potassium iodide solution to a test tube containing lead nitrate solution [NCERT p.2]. A bright yellow precipitate of lead iodide forms instantly. Activity 1.2 (Precipitation Reaction): एक test tube में रखे lead nitrate solution में potassium iodide solution मिलाएं [NCERT p.2]। तुरंत lead iodide का एक चमकदार पीला precipitate (अवक्षेप) बन जाता है।
- Activity 1.3 (Gas Evolution): Take zinc granules in a flask and add dilute hydrochloric acid or sulphuric acid [NCERT p.2]. You will observe bubbles of hydrogen gas forming around the zinc, and the flask becomes warm to the touch. Activity 1.3 (Gas Evolution): एक flask में zinc granules (जस्ते के दाने) लें और उसमें dilute hydrochloric acid या sulphuric acid मिलाएं [NCERT p.2]। आप देखेंगे कि zinc के चारों ओर hydrogen gas के बुलबुले बन रहे हैं, और flask छूने पर गर्म महसूस होता है।
From these activities, we establish that a chemical reaction has taken place if we observe any of the following changes [NCERT p.2]: इन activities से हम यह conclusion निकालते हैं कि यदि हमें निम्नलिखित में से कोई भी बदलाव दिखाई दे, तो वहाँ एक chemical reaction हुई है [NCERT p.2]:
- Change in state Change in state (state में change)
- Change in colour Change in colour (रंग में change)
- Evolution of a gas Evolution of a gas (गैस का निकास)
- Change in temperature Change in temperature (temperature में change)
Solution:
(a) Boiling of water is a physical change because it only changes the state from liquid to gas without creating new substances.
(b) Rusting of an iron gate is a chemical change because iron reacts with moisture and oxygen in the air to form a new reddish-brown compound (hydrated iron oxide, rust) with entirely different chemical properties [NCERT p.13]. निम्नलिखित में से chemical change की पहचान करें: (a) पानी का उबलना, (b) लोहे के फाटक में जंग लगना।
Solution:
(a) पानी का उबलना एक physical change है क्योंकि यह केवल liquid से gas में state बदलता है, कोई नया substance नहीं बनता।
(b) लोहे के फाटक में जंग लगना एक chemical change है क्योंकि लोहा हवा की moisture और oxygen के साथ react करके एक नया लाल-भूरा compound (hydrated iron oxide, जंग) बनाता है जिसके chemical properties पूरी तरह से अलग होते हैं [NCERT p.13]।
Why is a magnesium ribbon rubbed with sandpaper before burning in air? [NCERT p.6] जलने से पहले magnesium ribbon को sandpaper से क्यों रगड़ा जाता है? [NCERT p.6]
- Chemical changes yield new substances with entirely different chemical properties [NCERT p.1]. Chemical changes से नए substances बनते हैं जिनकी chemical properties बिल्कुल अलग होती हैं [NCERT p.1]।
- Signs of a chemical reaction include color changes, state changes, gas evolution, or temperature changes [NCERT p.2]. Chemical reaction के लक्षणों में रंग में बदलाव, state में बदलाव, गैस का निकलना या temperature में बदलाव शामिल हैं [NCERT p.2]।
- Activity 1.1 shows magnesium ribbon burns with a dazzling white flame to form magnesium oxide powder [NCERT p.1]. Activity 1.1 दर्शाता है कि magnesium ribbon एक चमकदार सफेद लौ के साथ जलकर magnesium oxide का सफेद पाउडर बनाती है [NCERT p.1]।
2. Chemical Equations रासायनिक समीकरण
Instead of describing a reaction in a long sentence, we represent it using a word-equation [NCERT p.2]:
Magnesium + Oxygen → Magnesium oxide
The substances that undergo chemical change are the reactants on the left-hand side (LHS), and the new substances formed are the products on the right-hand side (RHS) [NCERT p.2].
किसी reaction को लंबे वाक्यों में समझाने के बजाय, हम इसे एक word-equation (शब्द-समीकरण) के रूप में दर्शा सकते हैं [NCERT p.2]:
Magnesium + Oxygen → Magnesium oxide
वे substance जिनमें chemical change होता है, उन्हें left-hand side (LHS) पर reactants कहा जाता है, और जो नए substance बनते हैं, उन्हें right-hand side (RHS) पर products कहा जाता है [NCERT p.2]।
We make chemical equations more concise by using chemical formulas instead of words [NCERT p.3]:
Mg + O2 → MgO [Skeletal Equation] [NCERT p.3]
This is a skeletal chemical equation because the number of oxygen atoms on the LHS (2) does not equal the number of oxygen atoms on the RHS (1) [NCERT p.3].
हम शब्दों के स्थान पर chemical formulas का उपयोग करके chemical equations को अधिक संक्षिप्त बना सकते हैं [NCERT p.3]:
Mg + O2 → MgO [Skeletal Equation] [NCERT p.3]
यह एक skeletal chemical equation (ढांचागत समीकरण) है क्योंकि LHS पर oxygen atoms की संख्या (2) RHS पर oxygen atoms की संख्या (1) के बराबर नहीं है [NCERT p.3]।
Balancing Step-by-Step
To satisfy the Law of Conservation of Mass, the total number of atoms of each element must remain equal on both sides [NCERT p.3]. Law of Conservation of Mass को संतुष्ट करने के लिए, प्रत्येक तत्व के atoms की कुल संख्या दोनों ओर समान होनी चाहिए [NCERT p.3]।
Fe + H2O → Fe3O4 + H2
Solution:
- Step I: Draw boxes around each formula. Do not change anything inside the boxes [NCERT p.4]. Step I: प्रत्येक formula के चारों ओर बक्से (boxes) बनाएं। बक्से के अंदर कुछ भी न बदलें [NCERT p.4]।
- Step II: List the atoms of each element: Fe (LHS: 1, RHS: 3), H (LHS: 2, RHS: 2), O (LHS: 1, RHS: 4) [NCERT p.4]. Step II: प्रत्येक तत्व के atoms की सूची बनाएं: Fe (LHS: 1, RHS: 3), H (LHS: 2, RHS: 2), O (LHS: 1, RHS: 4) [NCERT p.4]।
-
Step III: Balance the element with the maximum atoms (Oxygen). Multiply H2O on the LHS by 4 to get 4 oxygen atoms [NCERT p.4]:
Fe + 4H2O → Fe3O4 + H2 Step III: सबसे अधिक atoms वाले तत्व (Oxygen) को balance करें। LHS पर H2O को 4 से गुणा करें ताकि 4 oxygen atoms हो सकें [NCERT p.4]:
Fe + 4H2O → Fe3O4 + H2 -
Step IV: Now balance Hydrogen. We have 8 H atoms on the LHS, so multiply H2 on the RHS by 4 [NCERT p.4]:
Fe + 4H2O → Fe3O4 + 4H2 Step IV: अब Hydrogen को balance करें। हमारे पास LHS पर 8 H atoms हैं, इसलिए RHS पर H2 को 4 से गुणा करें [NCERT p.4]:
Fe + 4H2O → Fe3O4 + 4H2 -
Step V: Finally, balance Iron. Multiply Fe on the LHS by 3 [NCERT p.5]:
3Fe + 4H2O → Fe3O4 + 4H2 Step V: अंत में, Iron को balance करें। LHS पर Fe को 3 से गुणा करें [NCERT p.5]:
3Fe + 4H2O → Fe3O4 + 4H2 - Step VI: Count atoms to verify. LHS has 3 Fe, 8 H, 4 O. RHS has 3 Fe, 8 H, 4 O. The equation is balanced! [NCERT p.5]. Step VI: सत्यापन के लिए atoms की गणना करें। LHS पर 3 Fe, 8 H, 4 O हैं। RHS पर 3 Fe, 8 H, 4 O हैं। समीकरण संतुलित है! [NCERT p.5]।
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Step VII (State Symbols): Write the physical states: solid (s), liquid (l), gas (g), and aqueous (aq) [NCERT p.5]:
3Fe(s) + 4H2O(g) → Fe3O4(s) + 4H2(g) [NCERT p.5] Here, (g) is used with H2O to indicate that water is used in the form of steam [NCERT p.5]. Step VII (State Symbols): उनकी physical stateएँ (physical states) लिखें: solid (s), liquid (l), gas (g), और aqueous (aq) [NCERT p.5]:
3Fe(s) + 4H2O(g) → Fe3O4(s) + 4H2(g) [NCERT p.5] यहाँ, H2O के साथ (g) का उपयोग यह दर्शाने के लिए किया गया है कि पानी का उपयोग भाप (steam) के रूप में किया गया है [NCERT p.5]।
Reactant Side (LHS)
Product Side (RHS)
In the balanced chemical equation 3Fe(s) + 4H2O(g) → Fe3O4(s) + 4H2(g), why is water written with state symbol (g)? [NCERT p.5] संतुलित chemical समीकरण 3Fe(s) + 4H2O(g) → Fe3O4(s) + 4H2(g) में पानी को physical state (g) के साथ क्यों लिखा गया है? [NCERT p.5]
- A chemical equation is a symbolic representation of a chemical reaction using chemical formulas [NCERT p.3]. Chemical equation chemical सूत्रों का उपयोग करके chemical reaction का एक symbolic representation है [NCERT p.3]।
- A skeletal equation is unbalanced, while a balanced equation has equal atoms of each element on both sides [NCERT p.3]. एक skeletal equation असंतुलित होती है, जबकि balanced equation में दोनों तरफ प्रत्येक तत्व के atoms की संख्या समान होती है [NCERT p.3]।
- Equations must be balanced to satisfy the Law of Conservation of Mass. State symbols (s, l, g, aq) add physical detail [NCERT p.5]. Law of Conservation of Mass को संतुष्ट करने के लिए समीकरणों को संतुलित करना आवश्यक है। physical state के संकेत (s, l, g, aq) physical विवरण जोड़ते हैं [NCERT p.5]।
3. Types of Chemical Reactions रासायनिक अभिक्रियाओं के प्रकार
During chemical reactions, atoms of one element do not change into those of another element, nor do they disappear [NCERT p.6]. Instead, chemical reactions involve the breaking and making of bonds between atoms to produce new substances [NCERT p.6]. Chemical reactions के दौरान, एक तत्व के atoms दूसरे तत्व के atoms में नहीं बदलते हैं, और न ही वे गायब होते हैं [NCERT p.6]। इसके बजाय, chemical reactions में नए substanceों को बनाने के लिए atoms के बीच bonds के टूटने और बनने की प्रक्रिया होती है [NCERT p.6]।
(संयोजन)
(अपघटन)
(विस्थापन)
(द्वि-विस्थापन)
(अपचयोपचय)
- Combination: Two single dancers join to dance as a pair.
- Decomposition: A dancing couple splits to dance alone.
- Displacement: A dancer comes in and displaces one partner from an active couple.
- Double Displacement: Two dancing couples switch partners [NCERT pp.6-12].
3.1 Combination Reaction संयोजन अभिक्रिया
A reaction in which a single product is formed from two or more reactants is called a combination reaction [NCERT p.6].
Example: Quick lime (calcium oxide) reacts vigorously with water to produce slaked lime (calcium hydroxide) [NCERT p.6]:
CaO(s) + H2O(l) → Ca(OH)2(aq) + Heat [NCERT p.6]
This reaction is highly exothermic because a large amount of heat is evolved, making the reaction mixture warm [NCERT p.6].
Ca(OH)2(aq) + CO2(g) → CaCO3(s) + H2O(l) [NCERT p.7]
3.2 Decomposition Reaction अपघटन अभिक्रिया
A reaction in which a single reactant breaks down to give simpler products is called a decomposition reaction [NCERT p.8]. It is the opposite of a combination reaction.
- Thermal Decomposition (ऊष्मीय अपघटन): Carried out by heating.
- Heating green ferrous sulphate crystals (FeSO4 • 7H2O) drives out water, changing the colour from green to white/brown. The salt then decomposes into solid ferric oxide (Fe2O3) and gases with a burning sulphur smell (SO2 and SO3) [NCERT p.8]:
2FeSO4(s) Heat → Fe2O3(s) + SO2(g) + SO3(g) [NCERT p.8] - Heating lead nitrate powder in a test tube releases brown fumes of nitrogen dioxide (NO2) gas and leaves yellow lead oxide [NCERT p.9]:
2Pb(NO3)2(s) Heat → 2PbO(s) + 4NO2(g) + O2(g) [NCERT p.9]
- Heating green ferrous sulphate crystals (FeSO4 • 7H2O) drives out water, changing the colour from green to white/brown. The salt then decomposes into solid ferric oxide (Fe2O3) and gases with a burning sulphur smell (SO2 and SO3) [NCERT p.8]:
- Electrolytic Decomposition (Electrolysis) (विद्युत अपघटन): Carried out by passing electric current.
- Passing electricity through water acidulated with dilute sulphuric acid splits water into hydrogen gas (H2) at the negative cathode and oxygen gas (O2) at the positive anode in a 2:1 volume ratio [NCERT p.9].
2H2O(l) Electricity → 2H2(g) + O2(g)
Figure 1.2 — Setup for the electrolysis of water, showing hydrogen gas collected at the cathode in double the volume of oxygen gas collected at the anode (Adapted from NCERT Fig 1.6, p. 9). - Passing electricity through water acidulated with dilute sulphuric acid splits water into hydrogen gas (H2) at the negative cathode and oxygen gas (O2) at the positive anode in a 2:1 volume ratio [NCERT p.9].
- Photolytic Decomposition (Photolysis) (प्रकाशीय अपघटन): Carried out by light energy.
- White silver chloride (AgCl) turns grey in sunlight as it decomposes into metallic silver and chlorine gas [NCERT p.9]. This is used in black-and-white photography [NCERT p.10]:
2AgCl(s) Sunlight → 2Ag(s) + Cl2(g) [NCERT p.9]
- White silver chloride (AgCl) turns grey in sunlight as it decomposes into metallic silver and chlorine gas [NCERT p.9]. This is used in black-and-white photography [NCERT p.10]:
3.3 Displacement Reaction विस्थापन अभिक्रिया
A reaction in which a more reactive element displaces or removes a less reactive element from its salt solution is known as a displacement reaction [NCERT p.11].
Example: Dipping an iron nail in copper sulphate solution. Iron, being more reactive than copper, displaces copper ions [NCERT p.11]:
Fe(s) + CuSO4(aq) → FeSO4(aq) + Cu(s) [NCERT p.11]
Similarly, zinc and lead are more reactive than copper, so they displace copper from its compounds [NCERT p.11]:
Zn(s) + CuSO4(aq) → ZnSO4(aq) + Cu(s) [NCERT p.11]
3.4 Double Displacement Reaction द्वि-विस्थापन अभिक्रिया
Reactions in which there is an exchange of ions between the reactants to form new compounds are called double displacement reactions [NCERT p.12].
Example: When sodium sulphate solution is mixed with barium chloride solution, a white, water-insoluble solid is formed instantly [NCERT p.11]. This insoluble substance is called a precipitate (अवक्षेप), and any reaction producing a precipitate is called a precipitation reaction (अवक्षेपण अभिक्रिया) [NCERT p.11]:
Na2SO4(aq) + BaCl2(aq) → BaSO4(s) ↓ + 2NaCl(aq) [NCERT p.11]
Here, the white precipitate of BaSO4 is formed by the reaction of barium ions (Ba2+) and sulphate ions (SO42-) [NCERT p.12].
3.5 Oxidation and Reduction उपचयन एवं अपचयन / रेडॉक्स
- Oxidation (उपचयन): The gain of oxygen or loss of hydrogen by a substance during a reaction [NCERT p.14].
- Reduction (अपचयन): The loss of oxygen or gain of hydrogen by a substance during a reaction [NCERT p.14].
If one reactant gets oxidised while the other gets reduced during a reaction, it is called an oxidation-reduction reaction or redox reaction (रेडॉक्स अभिक्रिया) [NCERT p.12].
Example: When black copper oxide (CuO) is heated in the presence of hydrogen gas, brown metallic copper is formed [NCERT p.12].
In this reaction, CuO loses oxygen and is reduced to Cu. Hydrogen (H2) gains oxygen and is oxidised to H2O [NCERT p.12].
Solution: Since two reactants (calcium oxide and water) combine to form a single product (calcium hydroxide), this is a Combination reaction [NCERT p.6].
Which of the following is correct regarding the respiration process in our body? [NCERT p.7]
- Combination reactions form one product. Decomposition splits one reactant using heat, light, or electricity [NCERT pp.6-9].
- Displacement reactions swap a less reactive metal with a more reactive one. Double displacement exchanges ions, often forming a precipitate [NCERT pp.11-12].
- Redox reactions involve simultaneous oxidation (oxygen gain/hydrogen loss) and reduction (oxygen loss/hydrogen gain) [NCERT p.12].
4. Everyday Oxidation दैनिक जीवन में उपचयन
4.1 Corrosion संक्षारण
When a metal is attacked by substances around it, such as moisture, air, and acids, it is said to corrode, and this process is called corrosion [NCERT p.13].
- Rusting of Iron: Iron articles are shiny when new, but get coated with a reddish-brown powder (hydrated ferric oxide, Fe2O3 • xH2O) when left in a humid atmosphere [NCERT p.13].
- Tarnishing of Silver: Silver articles develop a black coating (silver sulphide, Ag2S) when exposed to hydrogen sulphide gas in the air [NCERT p.13].
- Green Coating on Copper: Copper reacts with carbon dioxide and moisture in the air to form a green coating of basic copper carbonate (CuCO3 • Cu(OH)2) [NCERT p.13].
Corrosion causes massive damage to car bodies, bridges, iron railings, ships, and all objects made of metals, especially iron [NCERT p.13]. Corrosion के कारण कार की बॉडी, पुल, लोहे की रेलिंग, जहाजों और धातुओं (विशेषकर लोहे) से बनी सभी वस्तुओं को भारी नुकसान पहुँचता है [NCERT p.13]।
4.2 Rancidity विकृतगंधिता
When fats and oils are oxidised, they become rancid, and their smell, taste, and appearance change [NCERT p.13].
To prevent rancidity in food products, manufacturers use several techniques [NCERT p.13]:
- Adding antioxidants (उपचयन-रोधी) to foods containing fats and oils [NCERT p.13].
- Storing food in air-tight containers to slow down oxidation [NCERT p.13].
- Flushing packaging bags (like potato chips bags) with an inert gas like nitrogen to prevent oxidation of the fats [NCERT p.13].
Solution: Copper reacts with moist carbon dioxide and oxygen in the air, undergoing slow oxidation (corrosion) to form basic copper carbonate [CuCO3 • Cu(OH)2], which has a green color [NCERT p.13].
Why are potato chips packets flushed with nitrogen gas? [NCERT p.13]
- Corrosion is the slow eating away of metals by moist air, oxygen, or acids (e.g. rusting, tarnishing) [NCERT p.13].
- Rancidity is the oxidation of fats and oils in food, spoiling its taste, smell, and appearance [NCERT p.13].
- We prevent rancidity by adding antioxidants, vacuum packing, or flushing with inert nitrogen gas [NCERT p.13].
Checkpoint Quiz ज्ञान की परीक्षा
What You Can Now Do अब आप ये कर सकते हैं
Verify your understanding of this chapter by checking off these skills. You should be able to:
NCERT Solutions अभ्यास प्रश्नोत्तर
Below are the official exercise solutions for Class 10 Science Chapter 1: Chemical Reactions and Equations based on the CBSE curriculum. Click the button above to print or download these solutions as a clean PDF document.
(i) Hydrogen + Chlorine → Hydrogen chloride
(ii) Barium chloride + Aluminium sulphate → Barium sulphate + Aluminium chloride
(iii) Sodium + Water → Sodium hydroxide + Hydrogen
(ii) 3BaCl2(aq) + Al2(SO4)3(aq) → 3BaSO4(s) + 2AlCl3(aq)
(iii) 2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g)
(i) Name the substance 'X' and write its formula.
(ii) Write the reaction of the substance 'X' with water.
(ii) Calcium oxide reacts vigorously with water to produce slaked lime (calcium hydroxide), releasing a large amount of heat:
CaO(s) + H2O(l) → Ca(OH)2(aq) + Heat
2PbO(s) + C(s) → 2Pb(s) + CO2(g)
(a) Lead is getting reduced.
(b) Carbon dioxide is getting oxidised.
(c) Carbon is getting oxidised.
(d) Lead oxide is getting reduced.
Options: (i) a and b, (ii) a and c, (iii) a, b and c, (iv) all
Reason: Carbon oxide (CO2) is the product, not a reactant, so it is not oxidized. Lead (Pb) is a product, not a reactant, so it is not reduced. The actual reactants undergoing change are Carbon (getting oxidised to CO2) and Lead oxide (getting reduced to Pb).
(a) combination reaction, (b) double displacement reaction, (c) decomposition reaction, (d) displacement reaction.
Reason: Aluminium (Al) is more reactive than iron (Fe). It displaces iron from its oxide (Fe2O3) to form aluminium oxide (Al2O3).
(a) Hydrogen gas and iron chloride are produced.
(b) Chlorine gas and iron hydroxide are produced.
(c) No reaction takes place.
(d) Iron salt and water are produced.
Equation: Fe(s) + 2HCl(aq) → FeCl2(aq) + H2(g) ↑
Equations must be balanced to satisfy the Law of Conservation of Mass (discovered by Lavoisier), which states that matter cannot be created or destroyed in a chemical reaction. Therefore, the total mass of the reactants must equal the total mass of the products.
(a) Hydrogen gas combines with nitrogen to form ammonia.
(b) Hydrogen sulphide gas burns in air to give water and sulphur dioxide.
(c) Barium chloride reacts with aluminium sulphate to give aluminium chloride and a precipitate of barium sulphate.
(d) Potassium metal reacts with water to give potassium hydroxide and hydrogen gas.
(b) 2H2S(g) + 3O2(g) → 2H2O(l) + 2SO2(g)
(c) 3BaCl2(aq) + Al2(SO4)3(aq) → 2AlCl3(aq) + 3BaSO4(s)↓
(d) 2K(s) + 2H2O(l) → 2KOH(aq) + H2(g)
- Exothermic Reactions (ऊष्माक्षेपी अभिक्रिया): Reactions in which heat is released along with the formation of products.
Example: Burning of natural gas:
CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) + Heat - Endothermic Reactions (ऊष्माशोषी अभिक्रिया): Reactions in which energy is absorbed from the surroundings (in the form of heat, light, or electricity) to break bonds.
Example: Thermal decomposition of calcium carbonate:
CaCO3(s) + Heat → CaO(s) + CO2(g)
C6H12O6(aq) + 6O2(aq) → 6CO2(aq) + 6H2O(l) + Energy
Since energy/heat is released in this process, respiration is classified as an exothermic reaction.
2H2(g) + O2(g) → 2H2O(l)
In contrast, in a decomposition reaction, a single complex reactant splits apart under the influence of energy to form two or more simpler products:
2H2O(l) Electricity → 2H2(g) + O2(g)
Thus, the two reaction types are exact chemical opposites.
- Displacement Reaction: A single, more reactive element displaces a less reactive element from its compound:
Fe(s) + CuSO4(aq) → FeSO4(aq) + Cu(s)
Here, iron (Fe) alone displaces copper (Cu). - Double Displacement Reaction: Two chemical compounds react by exchanging their respective ions to form two new compounds:
Na2SO4(aq) + BaCl2(aq) → BaSO4(s) + 2NaCl(aq)
Here, sodium and barium exchange their partner anions (sulphate and chloride).
Example: Mixing sodium sulphate and barium chloride:
Na2SO4(aq) + BaCl2(aq) → BaSO4(s)↓ + 2NaCl(aq)
The barium ions (Ba2+) and sulphate ions (SO42-) react to form white, water-insoluble barium sulphate (BaSO4), which settles down at the bottom of the test tube.
CBSE Board PYQs विगत वर्षों के प्रश्न
(a) What changes in color will be observed?
(b) Identify the chemical formula of the residue left behind.
(b) The reddish-brown residue left behind is Ferric oxide (Fe2O3).
(i) H2S + Cl2 → 2HCl + S
(ii) 3MnO2 + 4Al → 3Mn + 2Al2O3
Reduced: Cl2 (chlorine) is reduced to HCl because it gains hydrogen.
(ii) Oxidized: Al (aluminium) is oxidized to Al2O3 because it gains oxygen.
Reduced: MnO2 (manganese dioxide) is reduced to Mn because it loses oxygen.
(b) Why is dilute sulphuric acid added to water during this process?
(c) Write the chemical equations representing the reactions at anode and cathode.
1. Take a plastic mug, drill two holes at its base, and fit rubber stoppers. Insert carbon electrodes.
2. Fill the mug with water so the electrodes are fully immersed. Add a few drops of dilute sulphuric acid.
3. Invert two test tubes filled with water over the electrodes. Connect electrodes to a 6V battery.
4. Switch on the current. You will observe bubbles collecting in both test tubes. The volume of gas at the cathode is double the volume at the anode.
(b) Reason for adding Acid: Pure water is a poor conductor of electricity (non-electrolyte). Adding dilute sulphuric acid makes the water highly conductive by releasing free hydronium (H3O+) and sulphate (SO42−) ions, facilitating electron flow.
(c) Electrode Reactions:
- At Cathode (Negative Electrode): 4H+(aq) + 4e- → 2H2(g) ↑ (Hydrogen gas)
- At Anode (Positive Electrode): 4OH-(aq) → 2H2O(l) + O2(g) ↑ + 4e- (Oxygen gas)